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Enrichment of erucic acid from pennycress (Thlaspi arvense L.) seed oil

Author:
Terry A. Isbell, Roque Evangelista, Steve E. Glenn, Drew A. Devore, Bryan R. Moser, Steven C. Cermak, Serin Rao
Source:
Industrial crops and products 2015 v.66 pp. 188-193
ISSN:
0926-6690
Subject:
Thlaspi arvense, biodiesel, crystallization, distillation, erucic acid, ethanol, fatty acid methyl esters, geographical distribution, growth habit, industrial crops, markets, methanol, potassium, seed oils, soaps, solvents, triacylglycerols, viscosity
Abstract:
Pennycress (Thlaspi arvense L.) is a winter annual that has a wide geographic distribution and a growth habit that makes it suitable for an off-season rotation between corn and soybeans in much of the Midwestern United States. Pennycress seed contains 36% oil with 36.6% erucic acid content There are a number of markets that pennycress could supply from an enriched erucic fatty acid fraction. Erucic acid was enriched using two independent separation methods; vacuum distillation of fatty acids or methyl esters and fractional crystallization of potassium soaps directly from the triglyceride. Fractional crystallization provided the highest level of purity, yielding an 87% erucic enriched fraction but in low theoretical recovery of 23% when ethanol was used as the crystallization solvent. A higher theoretical erucic recovery (59%) was obtained when methanol was used as a solvent yielding a 71% enriched erucic acid fraction. This method utilized a mixed solvent (90:10 methanol/water) for crystallization with a 5:1 solvent to analyte ratio. In an independent study, molecular distillation of the fatty acid methyl esters at 90°C, 7Pa of pressure enriched the erucic acid content to 67.1% in a single pass and could be further enriched to 71.6% with a second pass with an overall mass balance for this double distilled fraction of 43.2%. Distillation of the fatty acids was similar to the methyl esters yielding a fraction that contained 69.0% erucic with an overall mass balance of this fraction of 38.4% after two distillations. All three enriched fractions (feed, distilled FAME and mother liquor) were suitable for biodiesel; 40°C viscosity range 4.142–5.509, 100°C viscosity range of 1.713–2.095. Pour points were improved from the feed of −18°C to −27°C in the mother liquor fraction and remained the same in the distillate at −18°C. HFRR wear scars ranged from 120 to 177μm across all fractions.
Agid:
60489
Handle:
10113/60489