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Electroviscous Dissipation in Aqueous Electrolyte Films with Overlapping Electric Double Layers

Author:
Liu, F., Klaassen, A., Zhao, C., Mugele, F., van den Ende, D.
Source:
The Journal of physical chemistry 2018 v.122 no.2 pp. 933-946
ISSN:
1520-5207
Subject:
atomic force microscopy, electric field, electrophoresis, electroviscosity, hydrodynamics, ions, models, pH, salt concentration, silica
Abstract:
We use dynamic atomic force microscopy (AFM) to investigate the forces involved in squeezing out thin films of aqueous electrolyte between an AFM tip and silica substrates at variable pH and salt concentration. From amplitude and phase of the AFM signal we determine both conservative and dissipative components of the tip sample interaction forces. The measured dissipation is enhanced by up to a factor of 5 at tip–sample separations of ≈ one Debye length compared to the expectations based on classical hydrodynamic Reynolds damping with bulk viscosity. Calculating the surface charge density from the conservative forces using Derjaguin–Landau–Verwey–Overbeek (DLVO) theory in combination with a charge regulation boundary condition we find that the viscosity enhancement correlates with increasing surface charge density. We compare the observed viscosity enhancement with two competing continuum theory models: (i) electroviscous dissipation due to the electrophoretic flow driven by the streaming current that is generated upon squeezing out the counterions in the diffuse part of the electric double layer, and (ii) visco-electric enhancement of the local water viscosity caused by the strong electric fields within the electric double layer. While the visco-electric model correctly captures the qualitative trends observed in the experiments, a quantitative description of the data presumably requires more sophisticated simulations that include microscopic aspects of the distribution and mobility of ions in the Stern layer.
Agid:
6055495