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A bamboo-inspired hierarchical nanoarchitecture of Ag/CuO/TiO2 nanotube array for highly photocatalytic degradation of 2,4-dinitrophenol

Author:
Zhang, Xuhong, Wang, Longlu, Liu, Chengbin, Ding, Yangbin, Zhang, Shuqu, Zeng, Yunxiong, Liu, Yutang, Luo, Shenglian
Source:
Journal of hazardous materials 2016 v.313 pp. 244-252
ISSN:
0304-3894
Subject:
2,4-dinitrophenol, absorption, active sites, cupric oxide, irradiation, lighting, nanosheets, nanosilver, nanotubes, nitrophenols, photocatalysis, photocatalysts, photosynthesis, pollutants, silver, titanium dioxide
Abstract:
The optimized geometrical configuration of muitiple active materials into hierarchical nanoarchitecture is essential for the creation of photocatalytic degradation system that can mimic natural photosynthesis. A bamboo-like architecture, CuO nanosheets and Ag nanoparticles co-decorated TiO2 nanotube arrays (Ag/CuO/TiO2), was fabricated by using simple solution-immersion and electrodeposition process. Under simulated solar light irradiation, the 2,4-dinitrophenol (2,4-DNP) photocatalytic degradation rate over Ag/CuO/TiO2 was about 2.0, 1.5 and 1.2 times that over TiO2 nanotubes, CuO/TiO2 and Ag/TiO2, respectively. The enhanced photocatalytic activity of ternary Ag/CuO/TiO2 photocatalyst was ascribed to improved light absorption, reduced carrier recombination and more exposed active sites. Moreover, the excellent stability and reliability of the Ag/CuO/TiO2 photocatalyst demonstrated a promising application for organic pollutant removal from water.
Agid:
6069511