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Synthesis, crystal structure, and magnetic properties of the complex [(CH3)3NH]2 [Co(NCS)4] B A journal of chemical sciences

Author:
Jie, Yang, Yuan, Huang, YouQuan, Zhong, Ting, Fang, Fan, Hao, Qian, Kun, Ye, Yao-Hui
Source:
Zeitschrift für Naturforschung 2018 v.73 no.8 pp. 571-575
ISSN:
1865-7117
Subject:
X-ray diffraction, anions, cations, crystal structure, infrared spectroscopy, magnetic properties, magnetism
Abstract:
A new complex [(CH₃)₃NH]₂[Co(NCS)₄], in which zero-dimensional [Co(NCS)₄]ₙ²⁻ anions are balanced by 2n [(CH₃)₃NH]⁺ cations, was synthesized. The complex has been characterized by single X-ray diffraction, infrared spectroscopy, elemental analysis, and magnetic measurements. Magnetic susceptibility data indicate ferromagnetic interactions among the Coᴵᴵ ions.
Agid:
6081427