PubAg

Main content area

Vitamin B12 Catalyzed Atom Transfer Radical Addition

Author:
Proinsias, Keith ó, Jackowska, Agnieszka, Radzewicz, Katarzyna, Giedyk, Maciej, Gryko, Dorota
Source:
Organic letters 2018 v.20 no.1 pp. 296-299
ISSN:
1523-7052
Subject:
acrylates, alkenes, catalytic activity, chemical structure, halides, polymerization, vitamin B12
Abstract:
Vitamin B₁₂, a natural Co-complex, catalyzes atom transfer radical addition (ATRA) of organic halides to olefins. The established conditions were found to be very selective, with atom transfer radical polymerization (ATRP) occurring only in the case of acrylates.
Agid:
6083360