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Ni modified Pd nanoparticles immobilized on hollow nitrogen doped carbon spheres for the simehydrogenation of phenylacetylene

Author:
Wu, Wei, Zhang, Wei, Long, Yu, Qin, Jiaheng, Wen, He, Ma, Jiantai
Source:
Journal of colloid and interface science 2018 v.531 pp. 642-653
ISSN:
0021-9797
Subject:
carbon, catalysts, catalytic activity, industrial applications, models, nanoparticles, nickel, nitrogen, p-nitrophenol, styrene
Abstract:
In this work, Ni modified Pd nanoparticles immobilized on hollow nitrogen doped carbon spheres were successfully prepared, denoted as Pd/Ni-N/C. The Pd/Ni-N/C showed a moderate catalytic activity for the catalytic reduction of 4-nitrophenol as a model reaction. When applied for the simehydrogenation of phenylacetylene, the Pd/Ni-N/C exhibited a much better catalytic performance than some other Pd-based catalysts. What’s more, the selectivity of styrene could be kept at high levels even when the reaction time was prolonged. The superior catalytic performance may be ascribed to the incorporation of Ni and N species, which were detailedly characterized and contrastively demonstrated. The contained N groups could disperse and stabilize the supported metal nanoparticles. The Pd/Ni-N/C displayed no obvious decrease of catalytic activity and selectivity in the recycling tests, indicating the potential for various industrial applications.
Agid:
6094739