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TiC doped palladium/nickel foam cathode for electrocatalytic hydrodechlorination of 2,4-DCBA: Enhanced electrical conductivity and reactive activity

Author:
Lou, Zimo, Li, Yizhou, Zhou, Jiasheng, Yang, Kunlun, Liu, Yuanli, Baig, Shams Ali, Xu, Xinhua
Source:
Journal of hazardous materials 2019 v.362 pp. 148-159
ISSN:
0304-3894
Subject:
cathodes, coprecipitation, dechlorination, dissociation, electrical conductivity, electrolytes, foams, kinetics, nickel, operating costs, pH, palladium, silver, silver chloride, titanium
Abstract:
Titanium carbide (TiC) with excellent electrical conductivity, chemical and thermal stabilities has been recognized as one of the most promising electrocatalysts. A novel cathode, titanium carbide doped palladium/nickel foam (TiC-Pd/Ni foam), was synthesized via electroless deposition to improve the performance of Pd/Ni foam in electrocatlytic hydrodechlorination (ECH). TiC can be co-precipitated onto the surface of cathode during galvanic replacement reaction between Pd(II) solution and Ni foam. Both constant potential and constant current tests proved that TiC-Pd/Ni foam cathode performed remarkably higher activity for 2,4-dichlorobenzoic acid (2,4-DCBA) than Pd/Ni foam cathode, owing to the excellent conductivity of TiC and enhanced water dissociation over TiC-Pd/Ni foam cathode. Under the optimized reaction conditions of –0.85 V (vs Ag/AgCl), electrolyte of 10 mM and initial pH of 4, 99.8% of aqueous 2,4-DCBA (0.2 mM) was removed within 90 min. The removal process of the aqueous 2,4-DCBA obeyed first-order decay kinetic model. Over 86.3% of 2,4-DCBA can still be removed by TiC-Pd/Ni foam cathode in the fifth consecutive run within 120 min, which was much higher than that of Pd/Ni foam cathode (37.5%). Consequently, TiC-Pd/Ni foam cathode was a promising design for enhanced ECH activity and reduced operation cost.
Agid:
6144775