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D–A–D Structured Bis-acylhydrazone Exhibiting Aggregation-Induced Emission, Mechanochromic Luminescence, and Al(III) Detection

Author:
Santhiya, Kuppusamy, Sen, Shovan K., Natarajan, Ramalingam, Shankar, Ramasamy, Murugesapandian, Balasubramanian
Source:
Journal of organic chemistry 2018 v.83 no.18 pp. 10770-10775
ISSN:
1520-6904
Subject:
aluminum, cations, chemical reactions, chemical structure, luminescence, organic compounds
Abstract:
A readily accessible D–A–D triad molecule 1 was synthesized through acylhydrazone bond formation using carefully chosen building blocks. The molecule 1 exhibits emission through charge-coupled proton transfer and enhanced emission induced through aggregation and mechanochromic luminescence. Further, it detects Al(III) selectively among other cations in an efficient manner.
Agid:
6146162