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A four-component coupling reaction of carbon dioxide, amines, cyclic ethers and 3-triflyloxybenzynes for the synthesis of functionalized carbamates

Author:
Xiong, Wenfang, Qi, Chaorong, Cheng, Ruixiang, Zhang, Hao, Wang, Lu, Yan, Donghao, Jiang, Huanfeng
Source:
Chemical communications 2018 v.54 no.46 pp. 5835-5838
ISSN:
1364-548X
Subject:
amines, carbamates, carbon dioxide, chemical bonding, chemical reactions, cyclic ethers
Abstract:
A novel four-component coupling reaction of carbon dioxide, amines, cyclic ethers and 3-triflyloxybenzynes has been developed for the first time, providing an efficient method for the synthesis of a series of functionalized carbamate derivatives in moderate to high yields. The process proceeds under mild, transition metal-free and fluoride-free conditions, leading to the formation of two new C–O bonds, one new C–N bond and one C–H bond in a single step.
Agid:
6165710