PubAg

Main content area

Slow magnetic dynamics in a family of mononuclear lanthanide complexes exhibiting the rare cubic coordination geometry

Author:
AlexandropoulosD. I. A. and K. A. S. contributed equally to this work., Dimitris I., Schulte, Kelsey A., Vignesh, Kuduva R., Dunbar, Kim R.
Source:
Chemical communications 2018 v.54 no.72 pp. 10136-10139
ISSN:
1364-548X
Subject:
chemical compounds, chemical reactions, geometry, ions, magnetism
Abstract:
A new family of mononuclear lanthanide complexes, where the eight coordinate lanthanide ions adopt a very rare cubic coordination geometry is reported. The Dy analogue exhibits SMM behavior with a Uₑff value 95.7 K under a 0.02 T applied dc field. Ab initio calculations support the observed magnetic behavior.
Agid:
6166315