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Evidence for anion-binding of all-cis hexafluorocyclohexane in solution and solid state

Author:
Shyshov, Oleksandr, Siewerth, Kevin Andre, von Delius, Max
Source:
Chemical communications 2018 v.54 no.34 pp. 4353-4355
ISSN:
1364-548X
Subject:
X-ray diffraction, acetone, chemical reactions, chlorides, dielectric properties, nuclear magnetic resonance spectroscopy, solvents, stoichiometry
Abstract:
We report a solution NMR and X-ray crystallographic study on the anion affinity of all-cis 1,2,3,4,5,6-hexafluorocyclohexane, which has only recently become synthetically accessible. Our results suggest that the interaction exhibits preferential 1 : 1 stoichiometry, while its strength is only moderate (e.g. Kₐ = 400 M⁻¹ in acetone for Cl⁻) and depends mainly on the size of the anion and the dielectric constant of the solvent.
Agid:
6175011