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Foldamer-based helicate displaying reversible switching between two distinct conformers

Author:
Jeon, Hae-Geun, Lee, Hyun Kyung, Lee, Seungwon, Jeong, Kyu-Sung
Source:
Chemical communications 2018 v.54 no.45 pp. 5740-5743
ISSN:
1364-548X
Subject:
chemical compounds, chemical reactions, temperature
Abstract:
A new double-stranded dinuclear helicate that displays conformational switching in response to temperature was prepared by self-assembly of an aromatic helical foldamer and dichloropalladium(ii). The relative populations of the two helicate conformers, syn–anti and syn–syn, were demonstrated to be reversibly modulated through temperature control.
Agid:
6175227