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Foldamer-based helicate displaying reversible switching between two distinct conformers
- Jeon, Hae-Geun, Lee, Hyun Kyung, Lee, Seungwon, Jeong, Kyu-Sung
- Chemical communications 2018 v.54 no.45 pp. 5740-5743
- chemical compounds, chemical reactions, temperature
- A new double-stranded dinuclear helicate that displays conformational switching in response to temperature was prepared by self-assembly of an aromatic helical foldamer and dichloropalladium(ii). The relative populations of the two helicate conformers, syn–anti and syn–syn, were demonstrated to be reversibly modulated through temperature control.