PubAg

Main content area

Synthesis and structural characterization of the first neptunium based metal–organic frameworks incorporating {Np₆O₈} hexanuclear clusters

Author:
Martin, N. P., März, J., Feuchter, H., Duval, S., Roussel, P., Henry, N., Ikeda-Ohno, A., Loiseau, T., Volkringer, C.
Source:
Chemical communications 2018 v.54 no.51 pp. 6979-6982
ISSN:
1364-548X
Subject:
dicarboxylic acids, hydrolysis, ligands, neptunium
Abstract:
Successful synthesis of the first transuranium metal–organic frameworks (TRU-MOFs) involving tetravalent Np⁴⁺ is reported. These compounds were obtained from the controlled hydrolysis of Np⁴⁺ in the presence of dicarboxylate ligands. The final structures contain the [Np₆O₄(OH)₄(H₂O)₆]¹²⁺ unit, which were never crystallized before with tetravalent neptunium, associated with ditopic ligands.
Agid:
6175286