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A zeolite-like MOF based on a heterotritopic linker of imidazolyl, carboxyl and pyridine with a long-sought uks net on Schwarz's D-surface

Author:
Ye, Chun-Rong, Zheng, Ji, Li, Mian, Huang, Xiao-Chun
Source:
Chemical communications 2018 v.54 no.63 pp. 8769-8772
ISSN:
1364-548X
Subject:
azides, chemical reactions, pyridines, thiocyanates, zeolites
Abstract:
The title MOF features a potential uninodal zeolite net, uks, which has never been found for real zeolites or zeolite-like MOFs. This rare structure exhibits specific anion binding of N₃⁻ over SCN⁻ in water, which reverses the Hofmeister series.
Agid:
6177617