PubAg

Main content area

Selective synthesis of 2,5-bis(aminomethyl)furan via enhancing the catalytic dehydration–hydrogenation of 2,5-diformylfuran dioxime

Author:
XuThese authors contributed equally., Yongming, Jia, Xiuquan, Ma, Jiping, Gao, Jin, Xia, Fei, Li, Xiaofang, Xu, Jie
Source:
Green chemistry 2018 v.20 no.12 pp. 2697-2701
ISSN:
1463-9270
Subject:
acidity, furans, green chemistry
Abstract:
2,5-Bis(aminomethyl)furan as a promising monomer was efficiently synthesized in 94.1% yield from biomass-derived 2,5-diformylfuran dioxime. The high selectivity is likely to be a result of the controlled reaction pathway over Rh/HZSM-5, which enhanced the sequence of the dehydration–hydrogenation of 2,5-diformylfuran dioxime owing to the surface acidity on the HZSM-5 support.
Agid:
6182682