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Spin–orbit charge transfer intersystem crossing in perylenemonoimide–phenothiazine compact electron donor–acceptor dyads

Author:
ZhaoThese authors contributed equally to this work., Yingjie, Duan, Ruomeng, Zhao, Jianzhang, Li, Chen
Source:
Chemical communications 2018 v.54 no.87 pp. 12329-12332
ISSN:
1364-548X
Subject:
chemical compounds, chemical reactions, geometry
Abstract:
The spin–orbit charge transfer intersystem crossing (SOCT-ISC) of perylenemonoimide–phenothiazine compact dyads was shown to depend on the molecular geometry and the vector dipole orientations of the two chromophores, and the dyads show high triplet state quantum yields (57%).
Agid:
6192367