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Polyimide incorporated cyanate ester/epoxy copolymers for high‐temperature molding compounds

Author:
Wu, Fan, Song, Bo, Hah, Jinho, Tuan, Chia‐Chi, Moon, Kyoung‐Sik, Wong, Ching‐Ping
Source:
Journal of polymer science 2018 v.56 no.21 pp. 2412-2421
ISSN:
0887-624X
Subject:
composite polymers, cyanates, epoxides, glass transition temperature, resins
Abstract:
The rapid development of high‐power devices has driven the requirement for high‐temperature stable epoxy molding compounds. In this work, a designed polymer blend system consisting of cyanate ester/epoxy copolymers modified by polyimide (CE/EP‐PI) has been studied. Polyimide used in this study has shown excellent dispersity in the cyanate ester and epoxy copolymer network (CE/EP), exhibiting homogeneous phase with a denser polymer network structure. With this polymer blend structure, CE/EP‐PI system was proved to have a glass transition temperature as high as ~270 °C, increased modulus, and largely enhanced fracture toughness up to 2.06 MPa m¹/². CE/EP‐PI resins showed outstanding long‐term stability at high temperature with low mass loss and increased fracture toughness after aging at 200 °C. This work provides a novel insight into the development of molding compounds based on polymer blends system with excellent high‐temperature properties. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018, 56, 2412–2421
Agid:
6198257