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Cationic tri(ferrocenecarbonitrile)silver(I)

Author:
Strehler, Frank, Rüffer, Tobias, Noll, Julian, Schaarschmidt, Dieter, Hildebrandt, Alexander, Lang, Heinrich
Source:
Zeitschrift für Naturforschung 2018 v.73 no.11 pp. 759-764
ISSN:
1865-7117
Subject:
chemical structure, electrochemistry, silver
Abstract:
The synthesis of the tri-coordinated ferrocenecarbonitrile silver(I) complex [Ag(N≡CFc)₃]OTf (3) is reported. Its electrochemical behavior shows that the three ferrocenyl units are oxidized in a very close potential range. In addition, the molecular structure of 3 in the solid state is discussed, showing that silver(I) is exclusively coordinated by three ferrocenecarbonitrile molecules.
Agid:
6198515