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Metal Acetylacetonates as a Source of Metals for Aqueous Synthesis of Metal–Organic Frameworks

Author:
Avci-Camur, Ceren, Perez-Carvajal, Javier, Imaz, Inhar, Maspoch, Daniel
Source:
ACS sustainable chemistry & engineering 2018 v.6 no.11 pp. 14554-14560
ISSN:
2168-0485
Subject:
aluminum, ambient temperature, coordination polymers, iron, zirconium
Abstract:
Demand continues for environmentally sound, high-yielding processes for the large-scale production of metal–organic frameworks (MOFs). Here we describe the use of metal acetylacetonate complexes as an alternative source of metals for the aqueous synthesis of MOFs. We have synthesized several carboxylate-based Zr(IV)-(UiO-66-NH₂, Zr-fumarate, UiO-66-(OH)₂, UiO-66-COOH and UiO-66-(COOH)₂), Fe(III)-(MIL-88A) and Al(III)-(CAU-10) porous MOFs from their corresponding metal acetylacetonates in good yields (typically >85%) and, in some cases, at room temperature.
Agid:
6199380