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In Situ Tracking of Partial Sodium Desolvation of Materials with Capacitive, Pseudocapacitive, and Battery-like Charge/Discharge Behavior in Aqueous Electrolytes
- Srimuk, Pattarachai, Lee, Juhan, Budak, Öznil, Choi, Jaehoon, Chen, Ming, Feng, Guang, Prehal, Christian, Presser, Volker
- Langmuir 2018 v.34 no.44 pp. 13132-13143
- batteries, carbon, cations, desalination, electrochemistry, electrodes, energy, manganese oxides, nanopores, quartz crystal microbalance, sodium, solvents, titanium, water uptake
- Aqueous electrolytes can be used for electrical double-layer capacitors, pseudocapacitors, and intercalation-type batteries. These technologies may employ different electrode materials, most importantly high-surface-area nanoporous carbon, two-dimensional materials, and metal oxides. All of these materials also find more and more applications in electrochemical desalination devices. During the electrochemical operation of such electrode materials, charge storage and ion immobilization are accomplished by non-Faradaic ion electrosorption, Faradaic ion intercalation at specific crystallographic sites, or ion insertion between layers of two-dimensional materials. These processes may or may not be associated with a (partial) loss of the aqueous solvation shell around the ions. Our work showcases the electrochemical quartz crystal microbalance as an excellent tool for quantifying the change in effective solvation. We chose sodium as an important cation for energy storage materials (sodium-based aqueous electrolytes) and electrochemical desalination (saline media). Our data show that a major amount of water uptake occurs during ion electrosorption in nanoporous carbon, while battery-like ion insertion between layers of titanium disulfide is associated with an 80% loss of the initially present solvation molecules. Sodiation of MXene is accomplished by a loss of 90% of the number of solvent molecules, but nanoconfined water in-between the MXene layers may compensate for this large degree of desolvation. In the case of sodium manganese oxide, we were able to demonstrate the full loss of the solvation shell.