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Highly efficient conversion of CO₂ to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect

Author:
Li, Ming-Ran, Zhang, Ming-Chao, Yue, Tian-Jun, Lu, Xiao-Bing, Ren, Wei-Min
Source:
RSC advances 2018 v.8 no.68 pp. 39182-39186
ISSN:
2046-2069
Subject:
aluminum, ammonium salts, carbon dioxide, carbonates, catalysts, epoxides, synergism
Abstract:
An intensification of the “electrophile–nucleophile” synergistic effect was achieved in a microreactor for the coupling reaction of CO₂ and epoxides mediated by the binary Al complex/ternary ammonium salt catalyst system. The microreactor technology is proven to be a powerful tool for the preparation of cyclic carbonates with an improved reaction rate and a wide substrate scope.
Agid:
6221265