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Unexpected, photochemically induced activation of the tetrabutylammonium cation by hexachloroplatinate(iv)

Author:
Silalahi, Imelda H., Sethi, Navpreet K., Shafikov, Marsel Z., Chechik, Victor, Whitwood, Adrian C., Bruce, Duncan W.
Source:
Chemical communications 2018 v.54 no.97 pp. 13682-13685
ISSN:
1364-548X
Subject:
acetone, cations, photolysis, tetrabutylammonium compounds
Abstract:
A dinuclear, butadiene-bridged complex, trans-μ²:η²,η²-1,3-butadiene-bis(trichloroplatinate(ii)) (1) was unexpectedly obtained on photolysis of acetone solutions of (NBu₄)₂[PtCl₆].
Agid:
6246683