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N-doping of graphene: toward long-term corrosion protection of Cu

Ren, Siming, Cui, Mingjun, Li, Wensheng, Pu, Jibin, Xue, Qunji, Wang, Liping
Journal of materials chemistry A 2018 v.6 no.47 pp. 24136-24148
air, copper, corrosion, electrical properties, electrochemistry, electron transfer, graphene, nitrogen, oxidation
Despite the extraordinary impermeability of graphene, graphene fails to prevent the oxidation of Cu substrates under long-term air exposure owing to their high conductivity. Previous investigations showed that N-doped graphene could modulate the electrical properties of graphene while there has been no experimental example to investigate the protective performance of N-doped graphene to date. Here we demonstrate the synthesis and characterization of N-doped graphene with large-area atomic layers, and then evaluate its protective properties by both short- (electrochemical tests) and long-term (air exposure) corrosion tests. The results show that both short- and long-term corrosion are inhibited because incorporating nitrogen in graphene can decrease the conductivity of graphene and thus prevent the electron transport between Cu/N-doped graphene interfaces. Our finding provides a new protection method of graphene and will promote the basic research and applications of graphene.