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An overview of the total synthesis of africane-type sesquiterpenoids

Author:
Matsuda, Yutaka, Saikawa, Yoko, Nakata, Masaya
Source:
Tetrahedron letters 2018 v.59 no.25 pp. 2377-2386
ISSN:
0040-4039
Subject:
chemical reactions, chemical structure, chemists, decane, sesquiterpenoids
Abstract:
Africane-type sesquiterpenoids consist of a bicyclo[5.3.0]decane structure and have been isolated from various natural environments. Their characteristic CC bond motifs, including a seven-membered ring core, fascinate many synthetic organic chemists. Thirteen total syntheses have been reported over the past four decades. The purpose of this digest is to provide an overview of these total syntheses of africane-type sesquiterpenoids, with an emphasis on methods for constructing the seven-membered ring structure.
Agid:
6251183