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Carbon–nitrogen bond cleavage of pyridine with two molecular substituted allenoates: access to 2-arylpyrimidin-4(3H)-one

Author:
JinThese authors contributed equally to this work., Tao, Yuan, Hongdong, Su, Shikuan, Jia, Xueshun, Li, Chunju, Li, Jian, Fang, Jianhui
Source:
Chemical communications 2018 v.54 no.100 pp. 14128-14131
ISSN:
1364-548X
Subject:
benzene, chemical reactions, cleavage (chemistry), pyridines
Abstract:
A DABCO-catalyzed annulation reaction of pyridin-2-amine and substituted allenoates has been disclosed. This strategy allows for the ring-opening of a pyridine ring system and the formation of two new rings including a pyrimidinone ring and a benzene ring in an efficient manner.
Agid:
6259069