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Rhodium(iii) vs. cobalt(iii): a mechanistically distinct three-component C–H bond addition cascade using a Cp*Rhᴵᴵᴵ catalyst

Author:
Li, Ruirui, Ju, Cheng-Wei, Zhao, Dongbing
Source:
Chemical communications 2019 v.55 no.5 pp. 695-698
ISSN:
1364-548X
Subject:
alcohols, aldehydes, catalysts, chemical bonding, chemical reactions, cobalt, rhodium
Abstract:
Three-component C–H bond additions across two different coupling partners remain underdeveloped. Herein, we report the first three-component Rhᴵᴵᴵ-catalyzed C–H bond additions to a wide range of dienes and aldehydes. Our method constitutes a complementary access with Ellman's Coᴵᴵᴵ-catalytic system to homoallylic alcohols.
Agid:
6269213