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Facile reduction of carboxylic acids to primary alcohols under catalyst-free and solvent-free conditions

Author:
HarinathBoth the authors contributed equally to this work., Adimulam, Bhattacharjee, Jayeeta, Panda, Tarun K.
Source:
Chemical communications 2019 v.55 no.10 pp. 1386-1389
ISSN:
1364-548X
Subject:
alcohols, ambient temperature, carboxylic acids, chemical communication, chemical reactions, hydrogen, moieties, protocols
Abstract:
We report the development of a facile protocol for the deoxygenative hydroboration of aliphatic and aryl carboxylic acids to afford corresponding primary alcohols under solvent-free and catalyst-free conditions. The reaction proceeds under ambient temperature exhibits good tolerance towards various functional groups and generates quantitative yields. The plausible mechanism involves the formation of Lewis acid–base adducts as well as the liberation of hydrogen gas.
Agid:
6287769