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Air‐assisted liquid–liquid extraction coupled with dispersive liquid–liquid microextraction and a drying step for extraction and preconcentration of some phthalate esters from edible oils prior to their determination by GC

Author:
Khoshmaram, Leila, Abdolmohammad‐Zadeh, Hossein, Ghaffarzadeh, Elham
Source:
Journal of separation science 2019 v.42 no.3 pp. 736-743
ISSN:
1615-9306
Subject:
chemical species, cooking fats and oils, drying, gas chromatography, liquid-phase microextraction, nitrogen, phthalates, solvents
Abstract:
In this work, a new, cheap, simple, fast, and low organic solvent consuming procedure is proposed for isolation, enrichment, and gas chromatographic determination of some phthalate esters in edible oils. The method is based on a combination of air‐assisted liquid–liquid extraction and dispersive liquid–liquid microextraction followed by a drying step under N₂ gas. Several experimental parameters affecting both extraction and preconcentration steps were investigated and optimized. Under the optimum conditions for the proposed method, wide linear ranges (0.05–800 μg/L) and low detection limits (0.007–0.023 μg/L) were observed. The ranges of enrichment factors and extraction recoveries were 68–340 and 14–68%, respectively. Eventually, the target analytes were successfully determined in different edible oils using the proposed method.
Agid:
6296519