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An intramolecular C(sp³)–H imination using PhI–mCPBA

Author:
BoseEqually contributing authors., Anima, Maiti, Saikat, Sau, Sudip, Mal, Prasenjit
Source:
Chemical communications 2019 v.55 no.14 pp. 2066-2069
ISSN:
1364-548X
Subject:
chemical communication, chemical compounds, dehydrogenation, heat production, iodine
Abstract:
Herein, a highly exothermic primary amine–polyvalent iodine reaction has been used successfully for selective functionalization of acidic C(sp³)–H groups for a dehydrogenative C–H imination reaction by 4H elimination. Overall, C(sp³)–H imination at 1,5 distances was readily done via organocatalysis using PhI (10 mol%)–mCPBA under ambient conditions.
Agid:
6308040