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A cyanide-bridged wheel featuring a seven-coordinate Mo(iii) center

Author:
Kempe, David K., Dolinar, Brian S., Vignesh, Kuduva R., Woods, Toby J., Saber, Mohamed R., Dunbar, Kim R.
Source:
Chemical communications 2019 v.55 no.14 pp. 2098-2101
ISSN:
1364-548X
Subject:
X-radiation, chemical communication, chemical reactions, cyanides, molybdenum, nickel
Abstract:
A new cyclic molecule incorporating [Moᴵᴵᴵ(CN)₇]⁴⁻ has been characterized by single crystal X-ray methods, SQUID magnetometry and theoretical calculations. The wheel molecule [Moᴵᴵᴵ(CN)₇]₆[Ni(L)]₁₂(H₂O)₆ exhibits ferromagnetic Mo–Ni coupling which did not exist for the previously reported octacyanometallate analogue [Moᴵⱽ(CN)₈]₆[Ni(L)]₁₂(H₂O)₆. These results indicate that known supramolecular architectures incorporating octacyanometallates can be used as platforms for making new molecules incorporating seven-coordinate cyanide precursors.
Agid:
6308044