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Homogeneously-catalysed hydrogen release/storage using the 2-methylindole/2-methylindoline LOHC system in molten salt-organic biphasic reaction systems

Author:
Søgaard, Alexander, Scheuermeyer, Marlene, Bösmann, Andreas, Wasserscheid, Peter, Riisager, Anders
Source:
Chemical communications 2019 v.55 no.14 pp. 2046-2049
ISSN:
1364-548X
Subject:
catalysts, chemical communication, chemical compounds, chemical reactions, hydrogen, liquids, temperature
Abstract:
Ir-Complex catalysed hydrogen release/storage using a 2-methylindole/2-methylindoline Liquid Organic Hydrogen Carrier (LOHC) system is shown to be effective in a temperature range of 120 to 140 °C. In the form of a liquid–liquid biphasic reaction system with molten [PPh₄][NTf₂] as catalyst immobilisation phase, the applied cationic Ir-complex can be easily separated and recycled enabling a small amount of ionic catalyst solution to store/release a large amount of hydrogen.
Agid:
6308051