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Halogen bonding effects on the outcome of reactions at metal centres

Author:
Carreras, Lucas, Benet-Buchholz, Jordi, Franconetti, Antonio, Frontera, Antonio, van Leeuwen, Piet W. N. M., Vidal-Ferran, Anton
Source:
Chemical communications 2019 v.55 no.16 pp. 2380-2383
ISSN:
1364-548X
Subject:
chemical reactions, halogens, ligands, rhodium
Abstract:
Key findings regarding the effects of ligand preorganisation via halogen bonding on the outcome of reactions at rhodium are reported. An unprecedented halogen bonding-mediated oxidative addition of CAᵣ–I bonds to rhodium with efficient formation of cyclometallated species deserves special mention.
Agid:
6312513