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Solvent-assisted synthesis of a shape-persistent chiral polyaza gigantocycle characterized by a very large internal cavity and extraordinarily high amplitude of the ECD exciton couplet

Author:
Zgorzelak, Mikołaj, Grajewski, Jakub, Gawroński, Jacek, Kwit, Marcin
Source:
Chemical communications 2019 v.55 no.16 pp. 2301-2304
ISSN:
1364-548X
Subject:
chemical compounds, chemical reactions, hydrophobicity
Abstract:
A giant, chiral square-shaped octaimine macrocycle has been obtained in a controlled manner from readily available and inexpensive substrates: 9,10-diphenylanthracene-based dialdehyde and trans-1,2-diaminocyclohexane. Reduction of the polyimine led to a chiral octaamine characterized by a very large internal hydrophobic cavity.
Agid:
6312534