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Intermolecular, redox-neutral azidoarylation of alkenes via photoredox catalysis
- ChenJC and SZ contributed equally., Jian, Zhu, Shengqing, Qin, Jian, Chu, Lingling
- Chemical communications 2019 v.55 no.16 pp. 2336-2339
- alkenes, catalytic activity, protocols, pyridines, redox reactions, regioselectivity
- An intermolecular, redox-neutral azidoarylation of alkenes with pyridines and TMSN₃ has been reported via visible light-induced photoredox catalysis. This protocol utilized a radical addition/radical coupling sequence, allowing for facile and regioselective installation of versatile β-azido pyridines under redox-neutral and mild conditions.