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Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis

Author:
Yatham, Veera Reddy, Bellotti, Peter, König, Burkhard
Source:
Chemical communications 2019 v.55 no.24 pp. 3489-3492
ISSN:
1364-548X
Subject:
carboxylic acids, cerium, decarboxylation, hydrazine, photocatalysis
Abstract:
We report the cerium photocatalyzed radical decarboxylative hydrazination of carboxylic acids with di-tert-butylazodicarboxylate (DBAD). The operationally simple protocol provides rapid access to synthetically useful hydrazine derivatives and overcomes current scope limitations in the photoredox-catalyzed decarboxylation of carboxylic acids.
Agid:
6332169