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Factors that determine thione(thiol)–disulfide interconversion in a bis(thiosemicarbazone) copper(ii) complex

Author:
Jeong, Haewon, Kang, Yeji, Kim, Jin, Kim, Byung-Kwon, Hong, Seungwoo
Source:
RSC advances 2019 v.9 no.16 pp. 9049-9052
ISSN:
2046-2069
Subject:
copper, ligands, thiols, zinc
Abstract:
Solvent-, acidity-, and redox-responsive thione(thiol)–disulfide interconversion were achieved by a dinuclear copper(ii) complex bearing a bis(thiosemicarbazone) (bTSC) ligand. The role of copper(ii) ion coordination was rationalized by parallel comparison with a bare bTSC ligand and zinc(ii) bTSC complexes under identical reaction conditions.
Agid:
6345116