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Converting inert plastic waste into energetic materials: A study on the light-accelerated decomposition of plastic waste with the Fenton reaction

Author:
Chow, Cheuk-Fai, Wong, Wing-Leung, Chan, Ching-Wan, Chan, Chung-Sum
Source:
Waste management 2018 v.75 pp. 174-180
ISSN:
0956-053X
Subject:
Fourier transform infrared spectroscopy, catalysts, chemical reactions, energy, hydrogen peroxide, iron, oxidants, plastics, poly(vinyl chloride), polypropylenes, waste management, wastes
Abstract:
Better treatment and management strategies than landfilling are needed to address the large quantities of unrecycled plastic waste generated by daily human activities. Waste-to-energy conversion is an ideal benchmark for developing future large-scale waste management technologies. The present study explores a new approach for producing energetic materials by converting inert plastic waste into energy (thermal and mechanical energies) via a light-controlled process through the simple chemical activation of plastic waste, including polyethylene, polypropylene, and polyvinyl chloride. The inert and non-polar polymer surfaces of the plastics were modified by generating a number of sulfonic groups (SO3−) using chlorosulfuric acid, followed by grafting of Fe(III) catalyst onto the polymer chains to obtain activated polymer. Elemental analyses of these activated materials showed that the carbon-to-sulfur ratio ranged from 3:1 to 5:1. The FTIR spectra indicated the presence of CC bonds (vC=C: 1615–1630 cm−1) and SO bonds (vS=O: 1151–1167 cm−1) in the activated polymers after chemical reaction. These activated materials were energetic, as light could be used to convert them into thermal (1800–3200 J/g) and mechanical energies (380–560 kPa/g) using hydrogen peroxide as the oxidant under ambient conditions within 1 h.
Agid:
6346656