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SuFEx-based strategies for the preparation of functional particles and cation exchange resins

Author:
KassickAuthors contributed equally to this manuscript., Andrew J., Chen, Li, Kovaliov, Marina, Mathers, Robert T., Locklin, Jason, Averick, Saadyah
Source:
Chemical communications 2019 v.55 no.27 pp. 3891-3894
ISSN:
1364-548X
Subject:
cation exchange resins, hydrogen, hydrolysis, polymers, sulfates, sulfuric acid
Abstract:
A predictable and reproducible number of sulfuric acid sites have been achieved for cation exchange resins by employing a mild SuFEx-based reagent system to effect the hydrolysis of fluorosulfonated polymer beads. The resultant poly(hydrogen sulfate) beads effectively demonstrate their utility as cation exchange resins in ion-capture experiments. Furthermore, their polyfluorosulfonated precursors have also proven to be suitable substrates for traditional SuFEx-type click reactions in both small molecule and protein immobilization applications.
Agid:
6353606