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High-pressure synthesis and crystal structure of the mixed-cation borate Ga₄In₄B₁₅O₃₃(OH)₃

Author:
Vitzthum, Daniela, Huppertz, Hubert
Source:
Zeitschrift für Naturforschung 2019 v.74 no.4 pp. 357-363
ISSN:
1865-7117
Subject:
X-ray diffraction, borates, cations, crystal structure, crystallization, geometry
Abstract:
The mixed cation triel borate Ga₄In₄B₁₅O₃₃(OH)₃ was synthesized in a Walker-type multianvil apparatus at high-pressure/high-temperature conditions of 12.5 GPa and 1300°C. Although the product could not be reproduced in further experiments, its crystal structure could be reliably determined via single-crystal X-ray diffraction data. Ga₄In₄B₁₅O₃₃(OH)₃ crystallizes in the tetragonal space group I4₁/a (origin choice 2) with the lattice parameters a = 11.382(2), c = 15.244(2) Å, and V = 1974.9(4) ų. The structure of the quaternary triel borate consists of a complex network of BO₄ tetrahedra, edge-sharing InO₆ octahedra in dinuclear units, and very dense edge-sharing GaO₆ octahedra in tetranuclear units.
Agid:
6362646