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An approach for in situ qualitative and quantitative analysis of moisture adsorption in nanogram-scaled lignin by using micro-FTIR spectroscopy and partial least squares regression

Author:
Xiao, Teng, Yuan, Hanmeng, Ma, Qiang, Guo, Xin, Wu, Yiqiang
Source:
International journal of biological macromolecules 2019 v.132 pp. 1106-1111
ISSN:
0141-8130
Subject:
adsorption, dynamic vapor sorption method, least squares, lignin, mechanical properties, models, qualitative analysis, quantitative analysis, relative humidity, sorption isotherms, spectroscopy, water content
Abstract:
Moisture sorption has a great impact on the mechanical properties of lignin. To better characterize the moisture sorption of lignin, an approach for in situ qualitative and quantitative analysis of moisture adsorption in nanogram-scaled lignin by using micro-FTIR spectroscopy and partial least squares regression is introduced in this study. Spectra of nanogram-scaled lignin were collected within the relative humidity (RH) of 0%–92%. A qualitative analysis of these measured spectra confirmed the effective water sorption sites and determined spectral ranges related to moisture adsorption. Using these identified spectral ranges, a quantitative forecasting model for the moisture content (MC) of lignin was built and developed according to partial least square regression (R2, 0.9996; RMSECV, 0.408; RMSEP, 0.118). Furthermore, the water sorption isotherm of lignin was acquired using the established forecasting model in which a very positive correlation between the estimated and measured MCs was demonstrated using a dynamic vapor sorption (DVS) setup. The results confirmed the practicability and effectiveness of this in situ qualitative and quantitative analysis approach.
Agid:
6366261