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A metal- and oxidizing-reagent-free anodic para-selective amination of anilines with phenothiazines

Author:
Wu, Yan-Chen, Jiang, Shuai-Shuai, Song, Ren-Jie, Li, Jin-Heng
Source:
Chemical communications 2019 v.55 no.30 pp. 4371-4374
ISSN:
1364-548X
Subject:
ambient temperature, amination, electrochemistry, metals, moieties, phenothiazines
Abstract:
A highly para-selective amination of anilines with phenothiazines for producing various functionalized 10-aryl-10H-phenothiazines is reported. The oxidative amination reaction proceeds electrochemically at room temperature, thereby avoiding the use of metals and oxidizing reagents with excellent functional group tolerance and broad substrate scope.
Agid:
6368139