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Preparation of all-cellulose composites with optical transparency using the banana pseudostem as a raw material

Author:
Chávez-Guerrero, L., Vazquez-Rodriguez, S., Salinas-Montelongo, J. A., Roman-Quirino, L. E., García-Gómez, N. A.
Source:
Cellulose 2019 v.26 no.6 pp. 3777-3786
ISSN:
0969-0239
Subject:
Raman spectroscopy, X-ray diffraction, bananas, biopolymers, cellulose, cellulose fibrils, crystal structure, energy, hydrolysis, light microscopy, nanocomposites, petroleum, raw materials, scanning electron microscopy, transmittance
Abstract:
Biopolymers are intended to substitute the petroleum-based polymers and all-cellulose composite has emerged as a green alternative, especially if it can be prepared through a method consuming less energy and fewer chemicals. Here, a novel approach to obtain a nanocomposite film made of cellulose fibrils imbibed into a nanocellulose matrix is described. Banana pseudostem was used as raw material and characterized along with the resulting materials using scanning electron microscopy, optical microscopy and Raman spectroscopy, while the cellulose/nanocellulose film was studied through X-ray diffraction, UV–Vis-NIR spectroscopy and laser scanning microscopy. Results indicate that cellulose (fibrils) and nanocellulose (platelets), extracted from banana pseudostem were successfully purified using hydrolysis at a relatively low amount of chemicals. Transparent films made of a fibrils/nanoplatelets blend were prepared by the solution casting method, exhibiting a transmittance of ≈ 83–88% and a crystallinity index of ≈ 70, hence demonstrating the feasibility of this novel method to obtain cellulose/nanocellulose free-standing films.
Agid:
6368521