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AuPd bimetallic nanoparticle-supported carbon nanotubes for selective detection of dopamine in the presence of ascorbic acid

Author:
Yang, Haitang, Liu, Dandan, Zhao, Xiaoyu, Yang, Jing-He, Chang, Haibo, Xing, Ruimin, Liu, Shanhu
Source:
Analytical methods 2017 v.9 no.21 pp. 3191-3199
ISSN:
1759-9679
Subject:
analytical methods, ascorbic acid, carbon, carbon nanotubes, chemical reduction, dopamine, electrodes, gold, humans, nanocomposites, nanoparticles, palladium, urine
Abstract:
A carbon nanotube-supported AuPd bimetallic nanoparticle (AuPd/CNT) nanocomposite modified glassy carbon (GC) electrode was fabricated and its catalytic properties towards dopamine (DA) in the presence of ascorbic acid (AA) were studied. AuPd/CNTs were synthesized by the simple chemical reduction of Au and Pd salt precursors with CNTs. Under the optimal detection conditions, the amperometric i–t curve shows a linear response of DA over the range from 0.2 μM to 50 μM with a detection limit of 83 nM (S/N = 3) on AuPd/CNTs–Nafion/GCE. Furthermore, the developed sensor showed excellent anti-interference, reproducibility and stability, and was also proven to be feasible for DA determination in human urine samples, indicating the potential application of this nanocomposite for real sample analysis.
Agid:
6384762