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Sub-3 nm Rh nanoclusters confined within a metal–organic framework for enhanced hydrogen generation
- Zhang, Hui, Huang, Maolin, Wen, Jie, Li, Yanping, Li, Airong, Zhang, Lianhong, Ali, Arshid Mahmood, Li, Yadong
- Chemical communications 2019 v.55 no.32 pp. 4699-4702
- ammonia, coordination polymers, hydrogen production, hydrolysis, nanoparticles
- Ultrafine sub-3 nm Rh nanoclusters confined within a metal–organic framework (UIO-66) were constructed through a double-solvent host–guest strategy and achieved superior hydrogen generation via ammonia borane hydrolysis compared with Rh nanoclusters dispersed on the exterior walls.