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Sub-3 nm Rh nanoclusters confined within a metal–organic framework for enhanced hydrogen generation

Author:
Zhang, Hui, Huang, Maolin, Wen, Jie, Li, Yanping, Li, Airong, Zhang, Lianhong, Ali, Arshid Mahmood, Li, Yadong
Source:
Chemical communications 2019 v.55 no.32 pp. 4699-4702
ISSN:
1364-548X
Subject:
ammonia, coordination polymers, hydrogen production, hydrolysis, nanoparticles
Abstract:
Ultrafine sub-3 nm Rh nanoclusters confined within a metal–organic framework (UIO-66) were constructed through a double-solvent host–guest strategy and achieved superior hydrogen generation via ammonia borane hydrolysis compared with Rh nanoclusters dispersed on the exterior walls.
Agid:
6385104