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trans–cis Configuration regulated supramolecular polymer gels and chirality transfer based on a bolaamphiphilic histidine and dicarboxylic acids

Author:
Chen, Chunfeng, Wang, Tianyu, Fu, Yunzhi, Liu, Minghua
Source:
Chemical communications 2016 v.52 no.7 pp. 1381-1384
ISSN:
1364-548X
Subject:
gels, histidine, optical isomerism, polymers
Abstract:
Supramolecular polymer gels based on the co-assembly of bolaamphiphilic l-histidine(BolaHis) and dicarboxylic acids are dependent on the molar ratios, flexibility and cis–trans configuration of acid molecules. Thus, oligomerized rigid cis-maleic acid or flexible trans-cyclohexane dicarboxylic acid can form chiral supramolecular polymer gels with l-BolaHis.
Agid:
6386470