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A homochiral vanadium–salen based cadmium bpdc MOF with permanent porosity as an asymmetric catalyst in solvent-free cyanosilylation

Author:
Bhunia, Asamanjoy, Dey, Subarna, Moreno, José María, Diaz, Urbano, Concepcion, Patricia, Van Hecke, Kristof, Janiak, Christoph, Van Der Voort, Pascal
Source:
Chemical communications 2016 v.52 no.7 pp. 1401-1404
ISSN:
1364-548X
Subject:
adsorption, cadmium, carbon dioxide, catalysts, chemical reactions, hydrogen, porosity, topology
Abstract:
A homochiral vanadium–salen based MOF with the pcu topology is constructed via in situ synthesis under solvothermal conditions. The synthesized MOF exhibits BET surface areas of 574 m² g⁻¹, showing the highest H₂ adsorption capacity (1.05 wt% at 77 K, 1 bar) and the highest CO₂ uptake (51 cm³ g⁻¹ at 273 K, 1 bar) for currently known salen-based MOFs. This framework shows excellent performance as an asymmetric catalyst in solvent-free cyanosilylation.
Agid:
6386533