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On the nature of the stabilisation of the E⋯π pnicogen bond in the SbCl₃⋯toluene complex

Author:
Lo, Rabindranath, Švec, Petr, Růžičková, Zdeňka, Růžička, Aleš, Hobza, Pavel
Source:
Chemical communications 2016 v.52 no.17 pp. 3500-3503
ISSN:
1364-548X
Subject:
antimony, chemical compounds, chemical reactions, electrostatic interactions
Abstract:
The off-symmetrical structure of the toluene⋯SbCl₃ complex is a consequence of the off-centre location of σ-holes at the Sb atom. DFT-SAPT calculations have been used to determine the total interaction energies and their components. The characteristic features of the pnicogen bonding are due to the concert action of electrostatic and dispersion interactions.
Agid:
6386775