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Palladium-catalyzed C(sp³)–C(sp²) cross-coupling of homoleptic rare-earth metal trialkyl complexes with aryl bromides: efficient synthesis of functionalized benzyltrimethylsilanes

Author:
Cai, Guilong, Huang, Yingda, Du, Tingting, Zhang, Shaowen, Yao, Bo, Li, Xiaofang
Source:
Chemical communications 2016 v.52 no.31 pp. 5425-5427
ISSN:
1364-548X
Subject:
catalysts, catalytic activity, cross-coupling reactions, moieties, organobromine compounds, palladium, rare earth elements
Abstract:
The first C(sp³)–C(sp²) cross-coupling of rare-earth metal alkyl complexes with aryl bromides has been developed. This reaction was conducted at low catalyst loading (0.5 mol%) and exhibited a broad substrate scope, thus providing a facile method for the synthesis of benzyltrimethylsilanes with diverse functional groups.
Agid:
6387424