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Hybrid ultramicroporous materials (HUMs) with enhanced stability and trace carbon capture performance
- KumarThese authors contributed equally to this work., Amrit, Hua, Carol, Madden, David G., O’Nolan, Daniel, Chen, Kai-Jie, Keane, Lee-Ann J., Perry, John J., Zaworotko, Michael J.
- Chemical communications 2017 v.53 no.44 pp. 5946-5949
- carbon, carbon dioxide, chemical reactions, desorption, gases, pyrazines, sorption
- Fine-tuning of HUMs through pillar substitution can significantly enhance trace CO₂ sorption performance and stability. The resulting materials, exemplified by the new material TIFSIX-3-Ni, [Ni(pyrazine)₂(TiF₆)]ₙ, are shown through temperature programmed desorption experiments to remove trace quantities of CO₂ from moist gas mixtures.