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Hydrogen atom transfer from 1,2- and 1,3-diols to the cumyloxyl radical. The role of structural effects on metal-ion induced C–H bond deactivation

Author:
Martin, Teo, Salamone, Michela, Bietti, Massimo
Source:
Chemical communications 2019 v.55 no.36 pp. 5227-5230
ISSN:
1364-548X
Subject:
calcium, chemical bonding, chemical reactions, hydrogen, lithium, magnesium
Abstract:
Strong C–H bond deactivation toward HAT has been observed in the reactions of the cumyloxyl radical with 1,2- and 1,3-diols, following addition of Li⁺ and Ca²⁺. Weaker effects have been observed with Mg²⁺. The role of the substrate structure and of the metal ion in the formation of Lewis acid–base complexes is discussed.
Agid:
6391861